Helmholz Center group achieves long-term stability for perovskite solar cells

11 Nov 2025

Inter-layer coating by “fluorinated compound” also boosts efficiency to almost 27 per cent.

Fluorinated compound layer increases the stability of the solar cell. Click for info.

Perovskite solar cells are inexpensive to produce and generate a high amount of electric power per surface area. However, they are not yet stable enough, losing efficiency more rapidly than the silicon market standard. Now, an international team led by Prof. Dr. Antonio Abate of the Helmholz Center in Berlin (HZB) has dramatically increased their stability by applying a novel coating to the interface between the surface of the perovskite and the top contact layer.

This has boosted conversion efficiency to almost 27 per cent, which represents the state-of-the-art, says HZB. After 1,200 hours of continuous operation under standard illumination, no decrease in efficiency was observed. The study involved research teams from China, Italy, Switzerland and Germany and has been published in Nature Photonics.

“We used a fluorinated compound that can slide between the perovskite and the “Buckyball” (C60) contact layer, forming an almost compact monomolecular film,” said Abate. These “Teflon-like” molecular layers chemically isolate the perovskite layer from the contact layer, resulting in fewer defects and losses. Additionally, the intermediate layer increases the structural stability of both adjacent layers, particularly the C60 layer, making it more uniform and compact.

“It’s actually like the Teflon effect,” said Abate. “The intermediate layer forms a chemical barrier that prevents defects while still allowing the electric contact.”

Much of the experimental research was conducted by the first author, Guixiang Li, while he was a PhD student in Abate’s team. Guixiang Li is now a professor at Southeast University in Nanjing, China, and is continuing with the collaboration. The study also involved teams from École Polytechnique Fédérale de Lausanne (EPFL) and Imperial College London.

High efficiency and stability

Using this approach, perovskite solar cells can achieve a lab-scale efficiency of 27 per cent, says the HZB announcement, which is slightly higher than the 26 per cent efficiency without the intermediate layer. The increase in stability is huge: even after 1,200 hours of continuous illumination by a “standard sun”, this high efficiency does not decrease.

“1,200 hours correspond to one year of outdoor use,” said Abate. In the comparison cell without the “Teflon layer”, the efficiency dropped by 20 per cent after just 300 hours. The coating also provides exceptional thermal stability when aged for 1,800 hours at 85 °C and tested for 200 cycles between -40 °C and 85 °C.

“The idea of using such Teflon-like molecules to form an intermediate film has been on my mind since my postdoctoral days in Henry Snaith’s lab, who did pioneer research on the perovskite materials. At that time, in 2014, the efficiency was only 15 per cent, declining significantly within a few hours. We have made huge progress,” said Abate.