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Yb KGW Laser Crystal

17 Jul 2019

Description

Yb KGW Laser Crystal-has large absorption coefficient, low quantum defect, high absorption and emission cross section

The simple two-level electronic structure of the Yb ion avoids undesired loss processes such as upconversion, excited state absorption, and concentration quenching. Compared to the commonly used Nd:YAG crystal, Yb:KGW crystal has a much larger absorption bandwidth, 3 or 4 times longer emission lifetime in similar hosts with enhanced storage capacity, lower quantum defect and is more suitable for diode pumping than the traditional Nd-doped systems. The smaller Stokes shift reduces heating and increases the laser efficiency. In comparison with other Yb doped laser crystals such as Yb:YAG and Yb:YCOB crystals, Yb:KGW has a much higher (13-17 times) cross-section of absorption, lower quantum defect (~4%), a cross-section of emission that is 9 times higher than Yb: YCOB, and an emission band that is broader than Yb:YAG, a high nonlinear coefficient of refraction, and the highest slope efficiency (87%).

With the emergence of laser diode as the preferred pump source for inertial confinement fusion and the application and development of Yb3+ laser materials in communication and military, the research on Yb3+ laser materials will reach a climax. Yb3+: KGd(WO4)2 (Yb:KGW) is one of the most promising laser active materials. Yb:KGW crystal is expected to replace Nd:YAG crystal and Yb:YAG crystal in high power diode pumped laser system. Yb:KGW also has great potential for high power, short pulse time femtosecond lasers and their wide application.

Parameter

Chemical formula potassium gadolinium tungastate
Crystal structure monoclinic double tungstates
Density 7.27 g/cm3
Transmission range 0.35-5.5 μm
Mohs hardness 4 to 5
Refractive indices at 1060 nm ng = 2.037, np = 1.986, nm=2.033
 
Thermal conductivity Ka=2.6 W/mK, Kb=3.8 W/mK, Kc=3.4 W/mK
Thermal optical coefficient @1064 nm dnp/dT=-15.7 * 10-6 K-1
dnm/dT=-11.8 * 10-6 K-1
dng/dT=-17.3 * 10-6 K-1
Thermal expansion αa=4X10-6 /°C
αb=3.6X10-6 /°C
αc=8.5X10-6 /°C
Melting temperature 1075 °C
Absorbtion cross section 1.2X10-19 cm2
Stimulated emission cross section (E| |a) 2.6X10-20 cm2
Laser wavelength 1023-1060 nm
Lasing threshold 35 mW
Stark levels energy (in cm-1) of the 2F5/2 manifolds of Yb3+ @ 77 K 10682, 10471, 10188
Stark levels energy (in cm-1) of the 2F7/2 manifolds of Yb3+ @ 77K 535, 385, 163, 0
optical damage threshold, GW/cm2 20
Absorption peak wavelength, lpump, [nm] 981.2
Absorption linewidth, Dlpump, [nm] 3.7
Peak absorption cross-section, spump, [cm2] 1.2×10-19
Peak absorption coefficient, [cm-1] 26
Emission wavelength, lse, [nm] 1023
Emission linewidth, Dlse, [nm] 20
Peak emission cross-section, sse, [cm2] 2.8×10-20
Quantum effect, lpump/lse, [nm] 0.959
Fluorescence lifetime, tem, [ms] 0.6
Polarized-a-absorption-spectra-and-b-emission-spectra-along-the-refractive-index-principal-axis-of-Yb-KGW-crystal

Feature

1. The width of absorption line is wide, and the pump wavelength of LD pump source with phase matching can be obtained without strict temperature control;
2. The quantum defect is low, and the pump wavelength is very close to the laser output wavelength, which will lead to a large intrinsic laser slope efficiency, and the quantum efficiency is up to about 90% theoretically;
3. Because the pumped energy level is close to the upper laser level, the thermal load in the material without radiation relaxation is low, which is only one third of that of the same laser material doped with neodymium;
4. No excitation state absorption and upconversion, high light conversion efficiency;
5. Long fluorescence life, more than three times that of the same neodymium-doped laser material, is conducive to energy storage;

Application

1064nm

femtosecond Yb:KGW laser applicated in nonlinear microscopy

Yb-ion based femtosecond lasers operating around 1000 nm are particularly suited for biological imaging with high-resolution multiphoton excitation fluorescence, and third and second harmonic generation microscopy. They are a good alternative to commonly used Ti:sapphire lasers emitting in the 800 nm wavelength regime. Longer excitation wavelengths are desirable due to lower scattering and higher penetration depths in the biological tissue. In addition, the autofluorescence and bleaching are also largely reduced. Furthermore, the generated third and second harmonics fall into the visible range (rather than UV), resulting in higher throughput and a simpler detection scheme. On the other hand, wavelengths in the range of a Cr:forsterite laser at around 1200-1300 nm suffer from significant water absorption. At higher excitation powers that may cause photo-damage of biological tissues. Moreover, direct diode pumping of Yb-ion doped laser gain media considerably reduces the cost of a system in comparison to Ti:sapphire and Cr:forsterite lasers, which are usually pumped by expensive solid-state or fiber lasers.

Yb:KGW oscillators

The extended cavity oscillators offer straightforward approach towards the scaling of the peak power by lowering the repetition rate (typically below 30-40 MHz).Nonetheless, the increased influence of the nonlinear effects usually results in a trade-off between the pulse duration and the peak power (or pulse energy). So far, pulses with 2.3 MW peak power (1 μJ energy) have been delivered from a 10 MHz Yb:KYW bulk oscillator. The pulse duration, however, was limited to 430 fs. Similarly, pulses with 1.3 MW peak power and 323 fs duration were generated from a 23.7 MHz Yb:CALGO bulk oscillator. On the other hand, short pulses with 145 fs duration but at a reduced peak power of 0.16 MW (24 nJ energy) were demonstrated directly from a 27 MHz Yb:CALGO bulk oscillator. Recently we demonstrated 67 fs pulses with 3 W of average output power at a repetition rate of 77 MHz from an Yb:KGW bulk oscillator.

regenerative amplifiers

Watt-level high-repetition-rate Yb:KGW regenerative amplifiers use acousto-optic switching. The obtained pulse energies up to now are on the order of tens of microjoules.

CONTACT DETAILS
Nanjing Crylink Photonics Co.,Ltd
No.3, Hengda Road, Economic and Technological Development Zone, Nanjing, China
No.200,Zhaoxian Road,Jiading District,Shanghai City
Nanjing
Jiangsu
210038
China
Tel: (86)025-68790684
Fax: (86)025-68790685
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